Nylon PA 12 as a Delrin Alternative

Nylon PA 12 as a Delrin Alternative

Engineers and manufacturers often find themselves at a crossroads, deciding between well-established materials and emerging alternatives. Two such contenders that frequently come up in discussions are Delrin and Nylon PA 12. Delrin has long been favored for its excellent mechanical properties and ease of machining. However, advancements in 3D printing technologies have brought Nylon PA 12 into the spotlight as a formidable alternative.

This article explores the nuances of these two materials, delving into their mechanical properties, processing capabilities, and suitability for different applications. Depending on the intended application or project requirements you have in mind, the crucial differences between these two materials may lead you to believe that one is better suited for your specific needs. However, by comparing Delrin and Nylon PA 12, we will uncover why many engineers are considering a shift toward Nylon PA 12, especially when leveraging the advantages of additive manufacturing.

Delrin: A Brief Overview

Delrin, or POM-H, is a high-performance engineering plastic discovered by German chemist, Hemann Staudinger, in 1920 and later introduced to the market by DuPont in 1960. Delrin is created by distilling hydrocarbon fuels down into fractions. These fractions can then be combined with other catalysts through polymerization of formaldehyde, resulting in long polyoxymethylene chains.

Delrin is a preferred material for manufacturers using injection molding and CNC machining because it can be machined using 3-axis and 5-axis CNC machines. Although it can be 3D printed, it is not ideal due to its high melting point and significant warping during the cooling phase. This makes it less suitable for complex or intricate designs, requiring tight tolerances, thin walls, and deep cavities. Furthermore, because CNC machines have cylindrical tools, it can be difficult to design and cut 90-degree angles.

However, its high density, low friction coefficient, and resilient surface make it a common alternative to parts originally machined using metal. These properties contribute to Delrin’s outstanding wear resistance and ability to ensure substantial load without deforming. Moreover, Delrin has a low moisture absorption rate and high dimension retention ability, helping it maintain its shape and size when exposed to humid environments.

Delrin Applications

High Load Applications

  • Gears
  • Bushings
  • Conveyor Belts

High Moisture Environments

  • Pumps and Valves
  • Piping Fittings
  • Fuel System Parts

Electrical Components

  • Switches
  • Appliance Housing
  • Coil Holders
  • Electrical Insulator Parts

Delrin Properties

Delrin material properties vary by formulation. However, the mechanical properties of Delrin® 150, one of the most popular formulations, are:
PropertyValue
Density.0513 lbs/in³
Tensile Strength75 MPa
Flexural Strength80 MPa
Elongation at Break25%
Heat Deflection250-330 °F
Water Absorption.25%

Nylon PA 12: A Brief Overview

Nylon PA 12, also known as Polyamide 12, has become a game-changer for additive manufacturing applications because of its unique combination of properties and processability. Furthermore, the low melting point, minimal warping, and excellent layer adhesion during the printing process help maintain the structural integrity and dimensional accuracy of complex designs.

The history of Nylon PA 12 dates to the mid-20th century when it was initially developed for traditional manufacturing processes like injection molding. Its synthesis involves the polymerization of laurolactam, resulting in a polyamide with a twelve-carbon atom backbone that contributes to its advantageous properties. According to EuroPlas, the material’s “long chains of carbon atoms provide flexibility and toughness, enabling it to withstand impact and deformation. Additionally, the repeating units of amide groups connecting to the carbon atom offer strong intermolecular interactions, resulting in high tensile strength, chemical resistance, and excellent thermal stability.”

Along with the material’s unique composition, the compatibility of Nylon PA 12 became evident with evolving 3D printing technologies including Multi Jet Fusion (MJF) and Selective Laser Sintering (SLS). Fast forward to today’s 3D printing market and it is one of the most widely used materials in the world. One reason for this is the processing capabilities of Nylon PA 12. Additive manufacturing allows engineers to design and produce complex geometries that would be difficult or even impossible to achieve with traditional machining methods.”

Nylon PA 12 Applications

Nylon PA 12’s high tensile strength, flexibility, and chemical resistance make it ideal for automotive and industrial components that must endure mechanical loads, exposure to harsh chemicals, and extreme temperatures. This includes:
  • Under-the-hood parts
  • Clips, brackets, housing, gears, and bearings
  • Jigs, Fixtures, and tooling
  • Manifolds

Nylon PA 12’s biocompatible and lightweighting capabilities offer the medical industry reliable solutions. This includes:
  • Medical devices
  • Orthotics
  • Prosthetics

Nylon PA 12’s high-quality surface finish and customizability for consumer goods products are driven by its inherent material properties and compatibility with additive manufacturing technologies: Common Nylon PA 12 consumer goods applications include:
  • Protective gear and equipment
  • Thin-walled features
  • Wearable devices
  • Electronic casing and housing
  • Drone parts

Nylon PA 12 Properties

PropertyValue
Density1.01 g/cm3
Tensile Strength48 MPa
Flexural Strength70 MPa
Elongation at Break15-20%
Heat Deflection223-347 °F
Melting Point369 °F

Nylon vs. Delrin: Conclusion

While Delrin has long been a staple in traditional manufacturing due to its excellent mechanical properties and machinability, Nylon PA 12 offers several advantages, especially when leveraging 3D printing technologies. Its superior flexibility, chemical resistance, thermal stability, and ease of processing provide engineers and manufacturers with a versatile material that meets the demands of modern, complex, and customized applications. As additive manufacturing continues to evolve, Nylon PA 12 stands out as a forward-thinking choice for innovative and efficient production solutions.

Abrasion Resistance

Moisture Resistance

High Temperature Tolerance

Complex Geometries

Low Friction

3D Printing

Machinability

Wear Resistance

Nylon

Delrin

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